QUANTITATIVE CHARACTERISTICS OF THE REACTION ENVIRONMENT

Author(s): 
List of sections: 
Chemical science - Open specialized section
Mounth / Year: 
2015, апреля
Issue of the journal: 
5
Pages: 
31-33
Type of the article: 
Scientific article
Abstract: 

The parameters characterizing solvents, obtained by the kinetic, spectroscopic or thermodynamic methods are discussed. The comparison of parameters, obtained using different methods, shows that there is a linear dependence among some of them. It means that parameters obtained using different methods for different reaction series, reflect changes of the same micro-properties of the environment in terms of replacement of one solvent by another. A new parameter of the solvent nucleophilicity (U) is offered

Keywords: 
parameters of solvents, electrophilicity, nucleophilicity, Simonyan’s parameter – U.
References: 

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